We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
A new approach for mathematical modeling of chemical kinetics.
- Authors
BREBENEL, MARIUS; BERBENTE, CORNELIU
- Abstract
A new approach for describing chemical kinetics for reactions in gas phase is proposed, which removes some observed inconsistencies. This new approach is referring mainly to the law of mass actions in both forms, chemical equilibrium and reaction rate. A new interpretation of the activation energy is also given, so that the Arrhenius law becomes consistent with both Boltzmann statistic distribution and the definition of equilibrium constant. It will be shown that the activation energy is not a simple constant, it depends on the temperature at which the reaction begins.
- Subjects
CHEMICAL kinetics; MATHEMATICAL models; ARRHENIUS equation; EQUILIBRIUM constant (Chemistry); ACTIVATION energy
- Publication
Journal of Engineering Sciences & Innovation (JESI), 2023, Vol 8, Issue 1, p43
- ISSN
2537-320X
- Publication type
Article