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- Title
Copper hydroselenite nitrates (A<sup>+</sup>NO<sub>3</sub>)<sub>n</sub> [Cu(HSeO<sub>3</sub>)<sub>2</sub>] (A=Rb<sup>+</sup>, Cs<sup>+</sup> and Tl<sup>+</sup>, n=1, 2) related to Ruddlesden – Popper phases.
- Authors
Markovski, Mishel R.; Charkin, Dmitri O.; Siidra, Oleg I.; Nekrasova, Diana O.
- Abstract
Three new layered copper hydrogen selenite nitrates, (ANO3)[Cu(HSeO3)2] (A = Cs, and Tl), and (RbNO3)2[Cu(HSeO3)2] have been prepared via isothermal evaporation of concentrated nitric acid solutions. The Tl and Cs compounds adopt a motif related to previously known (NH4Cl)[Cu(HSeO3)2]; the structure of the Rb compound represents a new structure type. The structures of (ANO3)[Cu(HSeO3)2] (A = Cs, Tl), (RbNO3)2[Cu(HSeO3)2], and (NH4NO3)3[Cu(HSeO3)2] form a unique homological series distantly related to Ruddlesden – Popper series of layered perovskites.
- Subjects
COPPER; NITRATES; RUBIDIUM; COPPER chlorides; NITRIC acid; ACID solutions; SELENITES
- Publication
Zeitschrift für Kristallographie. Crystalline Materials, 2019, p749
- ISSN
2194-4946
- Publication type
Article
- DOI
10.1515/zkri-2019-0036