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- Title
Oxidative Dehydrogenation of Ethane: A Chemical Looping Approach.
- Authors
Neal, Luke M.; Yusuf, Seif; Sofranko, John A.; Li, Fanxing
- Abstract
The current study investigates a chemical-looping-based oxidative dehydrogenation (CL-ODH) concept for ethane-to-ethylene conversion. In this cyclic redox scheme, an oxide-based redox catalyst is used to selectively combust hydrogen from ethane dehydrogenation. As the hydrogen product limits ethane conversion, in situ oxidation of hydrogen enhances the ethane conversion and ethylene yield. Moreover, heat required in ODH is compensated by re-oxidation of the oxygen-deprived redox catalyst, enabling auto-thermal operation for the overall process. Compared to steam cracking, CL-ODH can potentially achieve higher efficiency with lower CO2 and NO x emissions. Silica and magnesia-supported manganese oxides are investigated. It is determined that unpromoted Mn/SiO2 and Mn/MgO redox catalysts exhibit low selectivity towards ethylene. The addition of promoters such as sodium and tungsten renders effective redox catalysts with satisfactory activity, selectivity, oxygen carrying capacity, and redox stability.
- Subjects
OXIDATIVE dehydrogenation; CHEMICAL-looping combustion; ETHANES
- Publication
Energy Technology, 2016, Vol 4, Issue 10, p1200
- ISSN
2194-4288
- Publication type
Article
- DOI
10.1002/ente.201600074