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- Title
Degradation during Mixing of Silica-Reinforced Natural Rubber Compounds.
- Authors
Kraibut, Ammarin; Kaewsakul, Wisut; Sahakaro, Kannika; Saiwari, Sitisaiyidah; Noordermeer, Jacques W. M.; Dierkes, Wilma K.
- Abstract
The optimal mixing conditions for silica-filled NR compounds dictate the need to proceed at a high temperature, i.e., 150 °C, to achieve a sufficient degree of silanization. On the other hand, natural rubber is prone to degradation due to mechanical shear and thermal effects during mixing, particularly at long exposure times. The present work investigates NR rubber degradation during mixing in relation to prolonged silanization times. The Mooney viscosity and stress relaxation rates, bound rubber content, storage modulus (G'), and delta δ were investigated to indicate the changes in the elastic/viscous responses of NR molecules related to rubber degradation, molecular chain modifications, and premature crosslinking/interaction. In Gum NR (unfilled), an increase in the viscous response with increasing mixing times indicates a major chain scission that causes a decreased molecular weight and risen chain mobility. For silica-filled NR, an initial decrease in the Mooney viscosity with increasing silanization time is attributed to the chain scission first, but thereafter the effect of the degradation is counterbalanced by a sufficient silanization/coupling reaction which leads to leveling off of the viscous response. Finally, the higher viscous response due to degradation leads to the deterioration of the mechanical properties and rolling resistance performance of tire treads made from such silica-filled NR, particularly when the silanization time exceeds 495 s.
- Subjects
RUBBER; CHAIN scission; TIRE treads; ROLLING friction; SILANIZATION; STRAINS &; stresses (Mechanics)
- Publication
Materials (1996-1944), 2024, Vol 17, Issue 2, p341
- ISSN
1996-1944
- Publication type
Article
- DOI
10.3390/ma17020341