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- Title
Effect of a chiral ligand in the self-assembly of subphthalocyanine-based metallosupramolecular capsules.
- Authors
Sánchez-Molina, Irene; Lucena-Alcalde, Guillermo; Claessens, Christian G.; Torres, Tomás
- Abstract
Subphthalocyanine-based metallosupramolecular capsules have been self-assembled employing a chiral phosphine ( S-BINAP). This ligand seems to provide an arrangement of the coordination positions of platinum that inverts the known process of chiral self-discrimination of subphthalocyanines, which is typically produced between the enantiomers of the macrocycle when a nonchiral ligand is used for the self-assembly. In this article, we describe preliminary studies on the effect of S-BINAP on the self-assembly subphthalocyanine capsules.
- Subjects
CHIRALITY; PHOSPHINE; LIGANDS (Chemistry); ENANTIOMERS; SUPRAMOLECULAR chemistry; MACROCYCLIC compounds
- Publication
Canadian Journal of Chemistry, 2014, Vol 92, Issue 8, p685
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/cjc-2014-0053