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- Title
Synthesis of K + and Na + Synthetic Sodalite Phases by Low-Temperature Alkali Fusion of Kaolinite for Effective Remediation of Phosphate Ions: The Impact of the Alkali Ions and Realistic Studies.
- Authors
Bellucci, Stefano; Eid, Mohamed Hamdy; Fekete, Ilona; Péter, Szűcs; Kovács, Attila; Othman, Sarah I.; Ajarem, Jamaan S.; Allam, Ahmed A.; Abukhadra, Mostafa R.
- Abstract
Two sodalite phases (potassium sodalite (K.SD) and sodium sodalite (Na.SD)) were prepared using alkali fusion of kaolinite followed by a hydrothermal treatment step for 4 h at 90 °C. The synthetic phases were characterized as potential adsorbents for PO43− from the aqueous solutions and real water from the Rákos stream (0.52 mg/L) taking into consideration the impact of the structural alkali ions (K+ and Na+). The synthetic Na.SD phase exhibited enhanced surface area (232.4 m2/g) and ion-exchange capacity (126.4 meq/100 g) as compared to the K.SD phase. Moreover, the Na.SD phase exhibited higher PO43− sequestration capacity (Qmax = 261.6 mg g−1 and Qsat = 175.3 mg g−1) than K.SD phase (Qmax = 201.9 mg g−1 and Qsat = 127.4 mg g−1). The PO43− sequestration processes of both Na.SD and K.SD are spontaneous, homogenous, and exothermic reactions that follow the Langmuir isotherm and pseudo-first-order kinetics. Estimation of the occupied active site density validates the enrichment of the Na.SD phase with high quantities of active sites (Nm = 86.1 mg g−1) as compared to K.SD particles (Nm = 44.4 mg g−1). Moreover, the sequestration and Gaussian energies validate the cooperation of physisorption and weak chemisorption processes including zeolitic ion exchange reactions. Both Na.SD and K.SD exhibit significant selectivity for PO43− in the coexisting of other common anions (Cl−, SO42−, HCO3−, and NO3−) and strong stability properties. Their realistic application results in the complete adsorption of PO43- from Rákos stream water after 20 min (Na. SD) and 60 min (K.SD).
- Subjects
ALKALI metal ions; ION bombardment; SODALITE; EXOTHERMIC reactions; KAOLINITE; ION-permeable membranes
- Publication
Inorganics, 2023, Vol 11, Issue 1, p14
- ISSN
2304-6740
- Publication type
Article
- DOI
10.3390/inorganics11010014