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- Title
An unusual case of OD-allotwinning: 9,9'-(2,5-dibromo-1,4-phenylene)bis[9H-carbazole].
- Authors
Kautny, Paul; Schwartz, Thomas; Stöger, Berthold; Fröhlich, Johannes
- Abstract
9,9'-(2,5-Dibromo-1,4-phenylene)bis[9H-carbazole] (1) crystallizes as a category I order-disorder (OD) structure composed of non-polar layers of one kind with B2/m(1)1 layer symmetry. The crystals are made up of the two polytypes with a maximum degree of order (MDO). The monoclinic MDO1 polytype (B21/d) possesses an orthorhombic B-centered lattice and appears in two orientations, which are related by reflection at (100). The orthorhombic MDO2 polytype (F2dd) has a doubled b-axis and appears in two orientations, which are related by inversion. The crystal structures of both polytypes were determined in a concurrent refinement. The MDO1:MDO2 ratio is 69:31.
- Subjects
TWINNING (Crystallography); ORDER-disorder models; CARBAZOLE
- Publication
Acta Crystallographica Section B: Structural Science, Crystal Engineering & Materials, 2017, Vol 73, Issue 1, p65
- ISSN
2052-5192
- Publication type
Article
- DOI
10.1107/S2052520616018291