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- Title
Metal-Chelating N, N′-Bis(4-dimethylaminophenyl)acetamidinyl Radical: A New Chromophore for the Near-Infrared Region.
- Authors
Ehret, Fabian; Bubrin, Martina; Záliš, Stanislav; Kaim, Wolfgang
- Abstract
A new non-innocent ligand redox system, N, N′-bis(4-dimethylaminophenyl) substituted acetamidinato/acetamidinyl, has been designed and described by example of structurally and spectroscopically characterized ruthenium complexes. The hitherto unreported ligand is responsible for rather intense and narrow absorptions in the near-infrared region of the one- and two-electron oxidized forms. The spectroscopic, computational, and first structural characterization of an amidinyl radical complex adds to the list of established N-based radical ligands.
- Subjects
CHELATING agents; LIGAND binding (Biochemistry); LIGANDS (Chemistry); OXIDATION-reduction reaction; RUTHENIUM
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 35, p12275
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201501875