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- Title
Highly Active Phosphine-Free Bifunctional Iron Complex for Hydrogenation of Bicarbonate and Reductive Amination.
- Authors
Thai, Trieu ‐ Tien; Mérel, Delphine S.; Poater, Albert; Gaillard, Sylvain; Renaud, Jean ‐ Luc
- Abstract
Based on a 'transition metal frustrated Lewis pair' approach, a cyclopentadienone iron tricarbonyl complex has been designed and applied in the reductive amination and hydrogenation of bicarbonate. This well-defined phosphine-free complex displays the best activities reported to date for an iron complex in the reduction of bicarbonate into formate and in reductive amination.
- Subjects
HYDROGENATION; PHOSPHINE; IRON compounds; BICARBONATE ions; AMINATION; TRANSITION metals; LEWIS pairs (Chemistry)
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 19, p7066
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201500720