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- Title
Ultimate cyclic voltammetry: an analytical examination of the reversible case.
- Authors
Oldham, Keith
- Abstract
Multi-scan cyclic voltammetry may lead eventually to a repetitive current-versus-potential graph. Here such 'ultimate' cyclic voltammograms are investigated mathematically for reversible electrode reactions. The voltammetric shapes, after an infinite number of cycles, are modelled and their characteristics are documented. It is predicted that the approach to truly repetitive behaviour, within an experimentally realistic length of time, requires that a specific condition-balancing the potential scan range to the initial concentrations-be satisfied.
- Subjects
CYCLIC voltammetry; ANALYTICAL chemistry; ELECTRODE reactions; PREDICTION models; ELECTRIC potential; ELECTRIC currents
- Publication
Journal of Solid State Electrochemistry, 2013, Vol 17, Issue 11, p2749
- ISSN
1432-8488
- Publication type
Article
- DOI
10.1007/s10008-013-2176-2