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- Title
Adsorptive removal of methyl orange from aqueous solution by hydrotalcite derived catalysts.
- Authors
Aider, Nadia; Djebarri, Baya; Touahra, Fouzia; Halliche, Djamila
- Abstract
The objective of our work is to study the adsorption of methyl orange dye over ZnAl2O4 and ZnO-ZnAl2O4 derived from hydrotalcite in order to highlight their potential as low-cost adsorbents for the treatment of water. The materials ZnAl2, Zn2Al were synthesized via co-precipitation method and were characterized using various characterization techniques, which showed that the obtained materials corresponds to the compounds of hydrotalcite. Different parameters were studied to optimize the process of methyl orange removal on samples derived from hydrotalcite, including the mass of the adsorbent, the contact time, the concentration, and pH. On the other hand, adsorption isotherms were studied using Langmuir and Freundlich models, as well as the effect of these solids on thermodynamic quantities. According to the results obtained, the ZnO-ZnAl2O4 has the greatest adsorption capacity compared to the ZnAl2O4. The interaction of these materials with the dye shows that the adsorption kinetics are fast and follows a second-order adsorption rate expression. The maximum adsorption capacity determined by the Langmuir mathematical model is about 62.85 mg/g for ZnO-ZnAl2O4 and 46.24 mg/g for ZnAl2O4 and the thermodynamic study led to the conclusion that the adsorption is endothermic and that the adsorption process is spontaneous.
- Subjects
HYDROTALCITE; AQUEOUS solutions; ADSORPTION kinetics; ADSORPTION isotherms; ADSORPTION capacity; MIXED oxide catalysts; SORBENTS
- Publication
Desalination & Water Treatment, 2023, Vol 316, p185
- ISSN
1944-3994
- Publication type
Article
- DOI
10.5004/dwt.2023.30185