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- Title
Polymer-Immobilized Clusters and Metal Nanoparticles in Catalysis.
- Authors
Dzhardimalieva, G. I.; Zharmagambetova, A. K.; Kudaibergenov, S. E.; Uflyand, I. E.
- Abstract
Recent advances in the synthesis of polymer-immobilized clusters and metal nanoparticles and their use in catalysis of many organic reactions were presented. The main types of polymer-immobilized catalysts were considered, including cluster-containing polymers, polymer-protected metal nanoparticles fixed on inorganic supports, and gel-immobilized catalysts. Special attention was paid to the role of the polymer matrix. It functions not only as a stabilizing agent that prevents the aggregation of nanoparticles and their leaching into the reaction medium, but also as a ligand in the coordination sphere of the metal site, which allows the advantages of homogeneous and heterogeneous catalysts to be combined in one catalyst.
- Subjects
METAL clusters; CATALYSIS; HETEROGENEOUS catalysts; STABILIZING agents; POLYMERS; METAL nanoparticles
- Publication
Kinetics & Catalysis, 2020, Vol 61, Issue 2, p198
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158420020044