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- Title
Highly Efficient One Pot Electrocatalytic Method for Transforming Alcohols to Nitriles.
- Authors
Shubina, E. N.; Kashparova, V. P.; Bukurova, V. S.; Kataria, Y. V.; Zhukova, I. Yu.
- Abstract
A one pot electrocatalytic method was developed for the oxidative transformation of alcohols into nitriles in a two-phase aqueous-organic medium: methylene chloride–aqueous sodium bicarbonate solution. Under the proposed conditions, the catalytic system 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl–pyridine base with the participation of ammonium iodide makes it possible to convert a wide range of alcohols into nitriles with good to excellent yields (81–99%) without the use of catalysts based on toxic metals, hazardous reagents and/or oxidizing agents. In the synthesis, ammonium iodide is simultaneously a source of nitrogen and iodine, and also functions as a component of the background electrolyte.
- Subjects
OXIDIZING agents; HEAVY metals; ALCOHOL; SODIUM bicarbonate; NITRILES; AMMONIUM
- Publication
Russian Journal of General Chemistry, 2023, Vol 93, Issue 10, p2498
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363223100031