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- Title
The effect of the [Na/(Na+K)] ratio on Fe speciation in phonolitic glasses.
- Authors
CICCONI, MARIA RITA; GIULI, GABRIELE; ERTEL-INGRISCH, WERNER; PARIS, ELEONORA; DINGWELL, DONALD B.
- Abstract
Natural iron-bearing sodic phonolitic melts represent an extreme compositional range of the effect of the [Na/(Na+K)] ratio on the geochemical behavior of Fe in volcanic systems. Yet phonolitic melts have not been well investigated. The glasses studied here have been synthesized from liquids equilibrated over a range of oxygen fugacity conditions [log10(...) from -0.68 to -11] to elucidate the role of the alkali ratio in influencing the local environment around both divalent and trivalent Fe. In this study, the Fe K-edge XAS spectra (XANES and EXAFS) have been employed, to constrain the Fe structural role (oxidation state, coordination number, bond distances) in phonolitic glasses as a function of synthesis temperature (T), [Na/(Na+K)] ratio (= 0.0, 0.25, 0.5, 0.75, 1.0) and redox state. We verify that at constant oxygen fugacity, the [Na/(Na+K)] ratio has a strong effect on the Fe3+/ (Fe2++Fe3+) ratio. The results obtained are parameterized and discussed in terms of the contrasting effects of T, ..., and alkali ratio.
- Subjects
IRON; PHONOLITE; ALKALIES; OXIDATION states; LIQUIDS
- Publication
American Mineralogist, 2015, Vol 100, Issue 7, p1610
- ISSN
0003-004X
- Publication type
Article
- DOI
10.2138/am-2015-5155