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- Title
Synthesis and structure of silver complexes [Ph( i-Pr)P] [AgI] and [PhMeP] [AgI].
- Authors
Sharutin, V.; Sharutina, O.; Senchurin, V.; Neudachina, A.
- Abstract
Complexes [Ph( i-Pr)P] [AgI] and [PhMeP] [AgI] were synthesized by the reaction of alkyl (triphenyl)phosphonium iodides with silver iodide in dimethyl sulfoxide. Triphenylalkylphosphonium cations have a tetrahedral configuration. Silver atoms in binuclear anions [AgI] are characterized by trigonal coordination, the iodine coordination number being 2 or 1. In the polymeric anions [AgI] the silver coordination number is 4 and that of iodine, 2, 3, or 4.
- Subjects
PHOSPHORUS compound synthesis; SILVER compounds; PHENYL compounds; IODIDES; CATIONS synthesis; ANIONS
- Publication
Russian Journal of General Chemistry, 2016, Vol 86, Issue 7, p1653
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363216070203