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- Title
Salicylic aldehyde and 2- N-tosylaminobenzaldehyde tetrazolyl hydrazones and their complexes.
- Authors
Levchenkov, S.; Popov, L.; Scherbakov, I.; Raspopova, E.; Morozov, A.; Burlov, A.; Kogan, V.
- Abstract
Tetrazolyl hydrazones of salicylic aldehyde and 2- N-tosylaminobenzaldehyde as well as zinc(II) and copper(II) complexes on their base have been prepared. Quantum-chemical simulation of tautomerism of the hydrazones in vacuum and in the solutions has been performed. IR and NMR spectroscopy and magnetochemistry studies have revealed that the complexes are mononuclear; however, weak intermolecular exchange interaction of the antiferromagnetic type has been detected in the copper(II) complexes.
- Subjects
HYDRAZONES; ZINC compounds; COPPER compounds; METAL complexes; MAGNETOCHEMISTRY; MOLECULAR interactions
- Publication
Russian Journal of General Chemistry, 2016, Vol 86, Issue 5, p1064
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363216050133