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- Title
Promoting of non-transition metal alkylation with organyl halides in the presence of binary systems based on an organometallic compound and a transition metal compound: I. Hypothetical stepwise scheme and verification of the system efficiency.
- Authors
Eremeev, I.
- Abstract
A hypothetical scheme has been proposed for the alkylation of non-transition metals with organyl halides in the presence of binary systems consisting of an organometallic compound and a transition metal compound. The scheme implies catalysis by transition metal atoms, small clusters, and subhalides adsorbed on the surface of metal to be alkylated. These particles are formed during the process as a result of interaction between the binary system components. The alkylation of commercial zinc powder with ethyl bromide has been used as a model reaction to demonstrate that the binary system ethylzinc bromide-copper(I) iodide is superior in its efficiency and experimental simplicity to all other examined methods for stimulation of the alkylation of elements with organyl halides yielding organometallic compounds.
- Subjects
ALKYL group; ALKYL compounds; ALKYLATION; ORGANYL groups; FUNCTIONAL groups
- Publication
Russian Journal of General Chemistry, 2014, Vol 84, Issue 8, p1561
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363214080222