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- Title
A Manganese Pre-Catalyst: Mild Reduction of Amides, Ketones, Aldehydes, and Esters.
- Authors
Kelly, Colin M.; McDonald, Robert; Sydora, Orson L.; Stradiotto, Mark; Turculet, Laura
- Abstract
A new ( N-phosphinoamidinate)manganese complex is shown to be a useful pre-catalyst for the hydrosilative reduction of carbonyl compounds, and in most cases at room temperature. The Mn-catalyzed reduction of tertiary amides to tertiary amines, with a useful scope, is demonstrated for the first time by use of this catalyst, and is competitive with the most effective transition-metal catalysts known for such transformations. Ketones, aldehydes, and esters were also successfully reduced under mild conditions by using this new Mn catalyst.
- Subjects
MANGANESE; KETONES; AMIDES; CATALYSTS; ESTERS; ALDEHYDES; CHEMICAL inhibitors
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 50, p16117
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201709441