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- Title
Selective Synthesis of Six Products from a Single Indolyl α-Diazocarbonyl Precursor.
- Authors
James, Michael J.; O'Brien, Peter; Taylor, Richard J. K.; Unsworth, William P.
- Abstract
Indolyl α-diazocarbonyls can be selectively cyclized to give six distinct products through the careful choice of catalyst and reaction conditions. A range of catalysts were used, including complexes of RhII, PdII, and CuII, as well as SiO2, to promote diazo decomposition and subsequent cyclization/rearrangement through a range of mechanistic pathways.
- Subjects
CARBONYL compounds; CHEMICAL synthesis; INDOLE; CATALYSTS; DIAZO compounds; RING formation (Chemistry); REARRANGEMENTS (Chemistry)
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 33, p9823
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201605337