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- Title
First example of an anrorc rearrangement of a pyrazolo[5,1- c][1,2,4]triazine involving a side chain.
- Authors
Didenko, V. V.; Ledenyova, I. V.; Shestakov, A. S.; Shikhaliev, Kh. S.
- Abstract
The article discusses the nucleophilic rearrangement of annelated azines involving the atoms of a side chain. It mentions that the structure of the compounds was proved by using X-ray analysis and the reaction of the product of aminomethylation with hydrazine hydrate gave the pyrazolyl derivative rather than tricyclic diazepine. It says that identification of the intermediate in the reaction occurs thru ANCORC mechanism.
- Subjects
REARRANGEMENTS (Chemistry); NUCLEOPHILIC reactions; ATOMIC models; HYDRAZINE; HYDRATES; INTERMEDIATES (Chemistry)
- Publication
Chemistry of Heterocyclic Compounds, 2010, Vol 46, Issue 6, p770
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1007/s10593-010-0584-0