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- Title
Ruthenium(II) complexes derived from 2-phenylthiazoline-4-carboxylic acid: structure and.
- Authors
Denizaltı, Serpil; Şen, Betül; Gökçe, Aytaç Gürhan; Çetinkaya, Bekir
- Abstract
Piano-stool ([( p-cymene)Ru(thz)Cl], 2) and six-coordinated ([Ru(thz)2(PPh3)2], 3) ruthenium complexes derived from 2-phenylthiazoline-4-carboxylic acid (Hthz, 1) were synthesized for the first time, and fully characterized using conventional methods. Also, the molecular structure of complex 3 was determined using X-ray analysis. These complexes were evaluated as catalysts for of carbonyl compounds in the presence of isopropyl alcohol and KO tBu. Complex 2 was found to be more active than 3 in . Copyright © 2016 John Wiley & Sons, Ltd.
- Subjects
RUTHENIUM compounds; CARBOXYLIC acids; CARBONYL compounds; METAL complexes; ISOPROPYL alcohol; THIAZOLINES
- Publication
Applied Organometallic Chemistry, 2016, Vol 30, Issue 5, p373
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.3442