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- Title
3- C-Hydroxymethyl- D-riburonic Acid Synthesis of the Branched-Chain Uronic Acid and comparison with a carbohydrate component of a naturally occurring bilirubin conjugate.
- Authors
Blackstock, Walter P.; Kuenzle, Clive C.; Eugster, Conrad H.
- Abstract
A novel carbohydrate has previously been isolated from human bile as a complex glycoside of bilirubin [1]. This compound has been tentatively identified as 3- C-hydroxymethyl- D-riburonic acid. To test this structural assignment the proposed branched-chain uronic acid was synthesized. Gas chromatographic and mass spectrometric comparison of the natural and synthetic materials indicated that the proposed structure, 3-C-hydroxymethyl-D-riburonic acid, did not apply to thc natural product.
- Publication
Helvetica Chimica Acta, 1974, Vol 57, Issue 4, p1003
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19740570406