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- Title
Colloid and Nanosized Catalysts in Organic Synthesis: XXII. Hydrogenation of Cycloolefins Catalyzed by Immobilized Transition Metals Nanoparticles in a Three-Phase System.
- Authors
Nebykov, D. N.; Popov, Yu. V.; Mokhov, V. M.; Latyshova, S. E.; Shcherbakova, K. V.; Nemtseva, N. V.; Shishkin, E. V.
- Abstract
The processes of unsaturated cyclic hydrocarbons hydrogenation in a three-phase gas-liquid-solid catalyst system in the presence of nanostructured nickel, cobalt, or iron catalysts in a flow reactor at 130°C and atmospheric pressure have studied. RX3Extra activated carbon, γ-Al2O3, NaX zeolite, and Purolite CT-175 cation-exchange resin have been used as supports; NaBH4 and NH2NH2·H2O were used as reducing agents. The catalytic activity of supported nanoparticles and their selectivity with respect to the product of exhaustive hydrogenation have been investigated.
- Subjects
METAL nanoparticles; TRANSITION metals; ORGANIC synthesis; CATALYST synthesis; CYCLOALKENES; ION exchange resins; HYDROGENATION
- Publication
Russian Journal of General Chemistry, 2019, Vol 89, Issue 10, p1985
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363219100013