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- Title
Comparative study of benzene, chlorobenzene, and aniline solvation by alcohol-alcohol and alcohol-alkane mixtures.
- Authors
Korolev, V. P.; Kasina, Yu. A.; Smirnova, N. L.
- Abstract
The heats of solution of benzene, chlorobenzene, and aniline in mixtures of methanol or n-decane with 1-butanol or 1-decanol were measured by the calorimetric method at 25°C. The resulting data were supplemented with published data for the same solutes in a mixture of hexane with 1-butanol. The standard heats of solution of the investigated substances are described by common equations with a new independent variable: The relative fraction of hydroxy groups in the solution for the following pairs of mixtures with the same common component (alcohol): hexane-1-butanol + 1-butanol-methanol, decane-1-butanol + 1-butanol-methanol, and decane-1-decanol + 1-decanol-methanol.
- Subjects
BENZENE; ANILINE; ALCOHOL; ALKANES; SOLVATION; SOLUTION (Chemistry)
- Publication
Russian Journal of General Chemistry, 2007, Vol 77, Issue 10, p1708
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363207100088