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- Title
Self-Assembly and Visible-Light Photocatalytic Properties of W/Nb Mixed-Addendum Polyoxometalate and Transition-Metal Cations.
- Authors
Huang, Peng; Qin, Chao; Wang, Xin‐Long; Sun, Chun‐Yi; Jiao, Yan‐Qing; Xing, Yan; Su, Zhong‐Min; Shao, Kui‐Zhan
- Abstract
Making light work: Three novel W/Nb mixed‐addendum polyoxometalates, which all contain the {SiNb3W9O40} cluster, have been synthesized by conventional aqueous methods. Visible‐light photocatalytic H2 evolution activity (see figure) was observed for two of the compounds, with H2PtCl6 as a cocatalyst and triethylamine as a sacrificial electron donor.
- Subjects
PHOTOCATALYSTS; VISIBLE spectra; SOLAR energy; VALENCE bands; HYDROGEN; ULTRAVIOLET-visible spectroscopy; SPECTRAL reflectance
- Publication
ChemPlusChem, 2013, Vol 78, Issue 8, p775
- ISSN
2192-6506
- Publication type
Article
- DOI
10.1002/cplu.201300175