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- Title
Impact of water absorption on the creep performance of epoxy/microcrystalline cellulose composites.
- Authors
Lavoratti, Alessandra; Bianchi, Otávio; Cruz, Joziel A.; Al‐Maqdasi, Zainab; Varna, Janis; Amico, Sandro Campos; Joffe, Roberts
- Abstract
Recently, considerable effort has been made to study cellulose/epoxy composites. However, there is a gap when it comes to understanding the post‐conditioning anomalous effect of moisture uptake on their mechanical and dynamic‐mechanical properties, and on their creep behavior. In this work, up to 10.0 wt% microcrystalline cellulose (MCC) was incorporated into epoxy resin by simple mixing and sonication. Epoxy/MCC composites were fabricated by casting in rubber silicone molds, and rectangular and dog‐bone test specimens were produced. The moisture uptake, dynamic mechanical, chemical, tensile, and creep behavior were evaluated. The incorporation of MCC increased the water diffusion coefficient. The changes in storage modulus and glass transition temperature, combined with Fourier‐transform infrared spectroscopy analysis, evidenced that water sorption in epoxies causes both plasticization and additional resin crosslinking, although the latter is prevented by the addition of MCC. The creep strain of the composites increased by 60% after conditioning, indicating that plasticization induced by water sorption plays an important role in the long‐term properties of the composites.
- Subjects
CREEP (Materials); MICROCRYSTALLINE polymers; EPOXY resins; CELLULOSE; STRAINS &; stresses (Mechanics); SILICONE rubber
- Publication
Journal of Applied Polymer Science, 2024, Vol 141, Issue 19, p1
- ISSN
0021-8995
- Publication type
Article
- DOI
10.1002/app.55365