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- Title
Towards inhibiting conductivity of Mo/PVDF composites through building MoO<sub>3</sub> shell as an interlayer for enhanced dielectric properties.
- Authors
Peng, Weiwei; Zhou, Wenying; Li, Ting; Zhou, Juanjuan; Yao, Tian; Wu, Hongju; Zhao, Xueting; Luo, Jin; Liu, Jiaxin; Zhang, Dongli
- Abstract
Polymer dielectrics have received increasing attention owing to their wide applications in electrical, microelectronic and energy storage fields. However, it remains a challenging to prepare polymer dielectrics with a high dielectric constant (ε) but low dissipation factor (tanδ). In this work, conductive molybdenum (Mo) particles were encapsulated by a thin layer of semi-conductive molybdenum trioxide (MoO3) with a wide bandgap of 3.28 eV via a facile thermal calcination way under air, and the gained core–shell structured Mo@MoO3 particles were composited with poly(vinylidene fluoride) (PVDF) to generate morphology-controllable high-ε but low loss composites. The large ε can be realized in the PVDF composites with the Mo@MoO3, and both the electric conductivity and tanδ of the composites are significantly restrained to rather low levels even at high filler loadings, and apparently decrease with increasing the MoO3' shell thickness. The significantly ameliorated dielectric performances can be ascribed to the presence of MoO3 interlayer preventing the Mo particles from direct contact with each other and simultaneously hindering the long-range electron migration. The developed Mo@MoO3/PVDF composites with a high ε but low loss are great potential applications for electrical industries and microelectronic industries.
- Subjects
DIELECTRIC properties; ELECTRIC conductivity; DIFLUOROETHYLENE; PERMITTIVITY; DIELECTRICS; DIELECTRIC loss; TUNGSTEN trioxide
- Publication
Journal of Materials Science: Materials in Electronics, 2022, Vol 33, Issue 18, p14735
- ISSN
0957-4522
- Publication type
Article
- DOI
10.1007/s10854-022-08393-5