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- Title
Synthetic utility of endocyclic cleavage reaction.
- Authors
Shino Manabe; Yukishige Ito
- Abstract
Existence of endocyclic cleavage reaction is now clearly shown from experimental evidence of endocyclic cleavage reaction as well as computational chemistry. Not only stereoelectronic factor, several factors could be main factors for endocyclic cleavage reaction. Endocyclic cleavage reaction is useful for 1,2-cis aminoglycoside formation, which is difficult by conventional glycosylation. By using endocyclic cleavage reaction, several glycosides with 1,2-cis aminoglycoside were prepared.
- Subjects
GLYCOSIDE synthesis; CHEMICAL reactions; COMPUTATIONAL chemistry; STEREOELECTRONIC control; AMINOGLYCOSIDES
- Publication
Pure & Applied Chemistry, 2017, Vol 89, Issue 7, p899
- ISSN
0033-4545
- Publication type
Article
- DOI
10.1515/pac-2016-0917