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- Title
H-Bonding Room Temperature Phosphorescence Materials via Facile Preparation for Water-Stimulated Photoluminescent Ink.
- Authors
Lou, Lingyun; Xu, Tianqi; Li, Yuzhan; Zhang, Changli; Wang, Bochun; Zhang, Xusheng; Zhang, Hean; Qiu, Yuting; Yang, Junyan; Wang, Dong; Cao, Hui; He, Wanli; Yang, Zhou
- Abstract
Pure organic room-temperature phosphorescence (RTP) materials built upon noncovalent interactions have attracted much attention because of their high efficiency, long lifetime, and stimulus-responsive behavior. However, there are limited reports of noncovalent RTP materials because of the lack of specific design principles and clear mechanisms. Here, we report on a noncovalent material prepared via facile grinding that can emit fluorescence and RTP emission differing from their components' photoluminescent behavior. Exciplex can be formed during the preparation process to act as the minimum emission unit. We found that H-bonds in the RTP system provide restriction to nonradiative transition but also enhance energy transformation and energy level degeneracy in the system. Moreover, water-stimulated photoluminescent ink is produced from the materials to achieve double-encryption application with good resolution.
- Subjects
PHOSPHORESCENCE; RAPID thermal processing; INK; TEMPERATURE; CONSTRUCTION materials
- Publication
Molecules, 2022, Vol 27, Issue 19, p6482
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules27196482