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- Title
Pinacol Rearrangement and Direct Nucleophilic Substitution of Allylic Alcohols Promoted by Graphene Oxide and Graphene Oxide CO<sub>2</sub>H.
- Authors
Gómez‐Martínez, Melania; Baeza, Alejandro; Alonso, Diego A.
- Abstract
Graphene oxide (GO) and carboxylic acid functionalized GO (GO-CO2H) have been found to efficiently promote the heterogeneous and environmentally friendly pinacol rearrangement of 1,2-diols and the direct nucleophilic substitution of allylic alcohols. In general, high yields and regioselectivities are obtained in both reactions using 20 wt % of catalyst loading and mild reaction conditions.
- Subjects
ALLYL alcohol; GRAPHENE oxide; CARBOXYLIC acids; PINACOL rearrangement; NUCLEOPHILIC substitution reactions; CARBOCATIONS; SUSTAINABLE chemistry
- Publication
ChemCatChem, 2017, Vol 9, Issue 6, p1032
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201601362