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- Title
Two New Organic-Inorganic Hybrid Compounds using Bi- and Mono-Nuclear Cu-H<sub>2</sub>biim Subunits to modify Keggin Anions.
- Authors
Ying, Jun; Sun, Na; Yan, Lei; Lin, Xiao‐Ling; Liu, Yu‐Jing; Yang, Yang; Xiao, Ru; Tian, Ai‐Xiang
- Abstract
Two new Keggin-based organic-inorganic hybrid compounds, namely [Cu8(H2biim)8(SiW12O40)2] ·7H2O ( 1) and [Cu2(H2biim)4(H2O)2(SiMo12O40)] ( 2) (H2biim = 2,2′-biimidazole), were hydrothermally synthesized by using the bi-imidazole ligand and Keggin anions, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra, and cyclic voltammetry. In compound 1, two H2biim ligands are fused by two Cu+ ions to form a dinuclear [Cu2(H2biim)2]4+ subunit. The Cu3-based dinuclear subunits are further connected by [SiW12O40]4- anions to construct a 1D chain. The other Cu1-based dimer acts as a supporting unit of the anion. Through changing [SiW12O40]4- to [SiMo12O40]4-, compound 2 was obtained, including discrete anions and mononuclear subunits [Cu(H2biim)2(H2O)]2+. The electrochemical behaviors of compounds 1 and 2 bulk-modified carbon paste electrodes ( 1- and 2-CPE) were studied.
- Subjects
ORGANIC compounds; INORGANIC compounds; BISMUTH; COPPER; KEGGIN anions; LIGAND binding (Biochemistry); SINGLE crystals; X-ray diffraction
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2014, Vol 640, Issue 5, p968
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201300470