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- Title
Synthesis and Characterization of Iron(II) Thiocyanate Complexes with Derivatives of the Tris(pyridine-2-ylmethyl)amine (tmpa) Ligand.
- Authors
Kisslinger, Sandra; Kelm, Harald; Zheng, Sipeng; Beitat, Alexander; Würtele, Christian; Wortmann, Ramona; Bonnet, Sylvestre; Herres-Pawlis, Sonja; Krüger, Hans-Jörg; Schindler, Siegfried
- Abstract
Abstract. A series of iron(II) dithiocyanate complexes containing the tripodal ligands L, [Fe(L)(NCS)2] (with L = 6-Me2tmpa, 6-Me2pmea, 6-Me2-Me2uns-penp, 6-Me2-uns-penp, Me2uns-penp, imine-uns-penp and TMG-uns-penp), analogous to the known SCO complex[Fe(tmpa)(NCS)2] were prepared and investigated. It was possible to structurally characterize [Fe(6-Me2pmea)(NCS)2], [Fe(6-Me2-Me2uns-penp)(NCS)2], [Fe(Me2uns-penp)(NCS)2], [Fe(imine-uns-penp)(NCS)2] and [Fe(TMG-uns-penp)(NCS)2]. Magnetic susceptibility and Mößbauer measurements showed that all seven compounds maintain their high-spin states between 300 and 5 K.
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2012, Vol 638, Issue 12/13, p2069
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201200237