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- Title
Ruthenium(II)-Catalyzed Oxidant-Free C-H Olefination of Aromatic Carboxamides with Allyl Acetate.
- Authors
Li, Feifei; Shen, Cong; Zhang, Jian; Wu, Ling; Zhuo, Xupeng; Ding, Liyuan; Zhong, Guofu
- Abstract
An inexpensive ruthenium-catalyzed direct C-H olefination of aromatic carboxamides with allyl acetate was developed. This external oxidant-free protocol provided an efficient route for the synthesis of useful trans-styrene derivatives in high to excellent yields. The olefination reaction exhibited excellent regioselectivities and allowed the presence of a wide range of functional groups, such as OMe, F, Cl, Br, I, CF3, NMe2, as well as NO2.
- Subjects
RUTHENIUM; PLATINUM group; TRANSITION metals; CARBOXAMIDES; ANTICONVULSANTS
- Publication
Advanced Synthesis & Catalysis, 2016, Vol 358, Issue 24, p3932
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201600569