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- Title
Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand.
- Authors
Arashiba, Kazuya; Nakajima, Kazunari; Nishibayashi, Yoshiaki
- Abstract
Novel molybdenum-dinitrogen complexes bearing a PNN-type pincer ligand are designed, prepared, and characterized spectroscopically. Molecular structures of molybdenum trichloride and molybdenum-dinitrogen complexes bearing trimethylphosphine are confirmed by X-ray analysis. Stoichiometric and catalytic reactions are investigated, where only a stoichiometric amount of ammonia is produced based on the molybdenum atom of the complexes. These results indicate that reactive behaviors of molybdenum-dinitrogen complexes are depending on the nature of the pincer ligands.
- Subjects
TRANSITION metal compounds synthesis; MOLYBDENUM; NITROGEN; LIGANDS (Chemistry); MOLECULAR structure; TRIMETHYLPHOSPHINE; STOICHIOMETRY; AMMONIA
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2015, Vol 641, Issue 1, p100
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201400117