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- Title
Relativistic effects in oxides and halides of transition and post-transition metals.
- Authors
Kozlova, S.; Ryzhikov, M.; Slepkov, V.
- Abstract
The review presents the experimental and theoretic data on relativistic effects in solids, which were the objects of S. P. Gabuda's studies. Coordination and cluster compounds are considered. Unique data obtained by nuclear magnetic resonance, vibrational spectroscopy, magnetochemistry and other methods are presented. The possibilities of the occurrence of polymorphic phase transitions, the Jahn-Teller effect, intermolecular interactions, and other effects due to the features of structure of relativistic wave functions are discussed.
- Subjects
HALIDES; TRANSITION metals; RELATIVISTIC effects in atoms; NUCLEAR magnetic resonance; VIBRATIONAL spectra; MAGNETOCHEMISTRY
- Publication
Journal of Structural Chemistry, 2016, Vol 57, Issue 2, p238
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476616020025