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- Title
Crystal structure of a novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex derived from 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol.
- Authors
Sheng, G.; Cheng, X.; You, Z.; Zhu, H.
- Abstract
A novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex [ZnL(μ-CHCOO) (μ-N)(N)], where L is the deprotonated form of 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol, is prepared and characterized by elemental analysis, infrared spectrum, and single crystal X-ray determination. The complex crystallizes in the triclinic space group $$P\bar 1$$, with unit cell dimensions a = 12.7196(5) Å, b = 13.6597(6) Å, c = 13.7214(5) Å, α = 65.700(1)°, β = 83.429(1)°, γ = 63.545(1)°, V = 1938.4(1) Å, Z = 2, GOOF = 1.013, R = 0.0456, and wR = 0.1032. Structural analysis shows that the distances among the adjacent zinc atoms are 3.282(1) Å and 3.213(1) Å. The zinc atoms are in distorted square pyramidal and trigonal bipyramidal coordinations.
- Subjects
CRYSTAL structure; ZINC compounds; METAL complexes; X-ray diffraction; SINGLE crystals spectra
- Publication
Journal of Structural Chemistry, 2014, Vol 55, Issue 6, p1106
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S002247661406016X