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- Title
Macroscopic Hexagonal Tubes of 3 d -4 f Metallocycles.
- Authors
Zhao, Lang; Zhang, Li; Li, Xiao-Lei; Tang, Jinkui; Wu, Jianfeng; Guo, Mei; Powell, Annie K.
- Abstract
The self-assembly of three giant hexagonal 3d-4f metallocycles with inner diameters of 16.4, 16.5, and 16.4 Å, is described. Hexagonal metallocycles were stacked along the crystallographic c axis, producing unique hexagonal macroscopic tubular single crystals. The assembly mechanism of the tubular crystals was investigated. Remarkably, all three hexagonal metallocycles show typical single-molecule magnet behavior, benefiting from the ferromagnetic couplings between the 3d and 4f ions.
- Subjects
METALLACYCLES; SINGLE molecule magnets; SINGLE crystals; X-ray diffraction; ANIONS
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 50, p15574
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201609539