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- Title
Extended O-Doped Polycyclic Aromatic Hydrocarbons.
- Authors
Stassen, Daphné; Demitri, Nicola; Bonifazi, Davide
- Abstract
The synthesis of O-doped benzorylenes, in which peripheral carbon atoms have been replaced by oxygen atoms, has been achieved for the first time. This includes key high-yielding ring-closure steps which, through intramolecular C−O bond formation, allow stepwise planarization of oligonaphthalenes. Single-crystal X-ray diffraction showed that the tetraoxa derivative forms remarkable face-to-face π-π stacks in the solid state, a favorable solid-state arrangement for organic electronics.
- Subjects
POLYCYCLIC aromatic hydrocarbons; CATALYTIC doping; CARBON cycle; TETRAOXYGEN; SINGLE crystals; X-ray diffraction
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 20, p5947
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201509517