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- Title
Recent Advances in Asymmetric Catalysis Using p‐Block Elements.
- Authors
Pramanik, Milan; Guerzoni, Michael G.; Richards, Emma; Melen, Rebecca L.
- Abstract
The development of new methods for enantioselective reactions that generate stereogenic centres within molecules are a cornerstone of organic synthesis. Typically, metal catalysts bearing chiral ligands as well as chiral organocatalysts have been employed for the enantioselective synthesis of organic compounds. In this review, we highlight the recent advances in main group catalysis for enantioselective reactions using the p‐block elements (boron, aluminium, phosphorus, bismuth) as a complementary and sustainable approach to generate chiral molecules. Several of these catalysts benefit in terms of high abundance, low toxicity, high selectivity, and excellent reactivity. This minireview summarises the utilisation of chiral p‐block element catalysts for asymmetric reactions to generate value‐added compounds.
- Subjects
ENANTIOSELECTIVE catalysis; ORGANIC synthesis; CATALYSIS; METAL catalysts; BISMUTH
- Publication
Angewandte Chemie, 2024, Vol 136, Issue 9, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202316461