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- Title
Photoreduction of o-benzoquinone moiety in mono- and poly(quinone methacrylate) and on the surface of polymer matrix pores.
- Authors
Len'shina, N.; Arsenyev, M.; Shurygina, M.; Chesnokov, S.; Abakumov, G.
- Abstract
The kinetics of photoreduction under the action of visible light of the 3,6-di- tert-butyl- o-benzoquinone moiety in methacrylic monomer, polymer, and in the graft layer on the surface of pores in the presence of different N, N-dimethylanilines has been studied. The reaction is accelerated with the increasing electron-donating ability of the amine. In the presence of N, N-dimethylaniline at 50-fold molar excess of the amine, the photoreduction in the porous polymer occurs three and four times faster than in the monomer and the polymer, respectively.
- Subjects
PHOTOREDUCTION; BENZOQUINONES; QUINONE; VISIBLE spectra; ELECTRON donors
- Publication
High Energy Chemistry, 2017, Vol 51, Issue 3, p209
- ISSN
0018-1439
- Publication type
Article
- DOI
10.1134/S0018143917030080