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- Title
Palladates of the [NHC⋅H][Pd(NH<sub>2</sub>)(CC)Cl<sub>2</sub>] Type as Effective Pre‐catalysts for the Formation of C−C and C−N Bonds.
- Authors
Ostrowska, Sylwia; Czapik, Agnieszka; Kwit, Marcin; Nolan, Steven P.
- Abstract
The environmentally friendly, simple synthesis of a family complexes of the general formula [NHC⋅H][Pd(NH2)(CC)Cl2] (CC=biphenyl) is presented. The catalytic activity of these air‐ and moisture‐stable complexes was evaluated as a function of the imidazolium counterion. These pre‐catalysts can be converted, under catalytic conditions, to Pd‐NHC species enabling the Suzuki–Miyaura, Sonogashira, and Buchwald–Hartwig amination reactions under very mild operating conditions.
- Subjects
CATALYTIC activity; PALLADIUM catalysts; AMINATION; MECHANICAL chemistry; BOND formation mechanism
- Publication
ChemCatChem, 2023, Vol 15, Issue 24, p1
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.202301124