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- Title
Potassium Persulfate‐Promoted N‐Nitrosation of Secondary and Tertiary Amines with Nitromethane under Mild Conditions.
- Authors
Azeez, Sadaf; Chaudhary, Priyanka; Sureshbabu, Popuri; Sabiah, Shahulhameed; Kandasamy, Jeyakumar
- Abstract
A simple and efficient route for the N‐nitrosation of various secondary amines with nitromethane is described in the presence of potassium persulfate and DBU. Under optimized condition, tertiary amines underwent a dealkylative N‐nitrosation with good yields. Inexpensive reagents, broad substrate scope and efficient conversion make the current protocol more attractive in organic synthesis. N‐Nitrosation of secondary and tertiary amines was achieved using nitromethane as s source of nitrous acid in the presence of K2S2O8 and DBU. Inexpensive reagents, broad substrate scope and excellent yields make the current protocol very attractive in organic synthesis.
- Subjects
POTASSIUM; NITROSATION; TERTIARY amines
- Publication
Asian Journal of Organic Chemistry, 2018, Vol 7, Issue 10, p2113
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201800437