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- Title
Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window.
- Authors
Song, Huimin; Wang, Naizheng; Li, Yunfei; Liu, Wang; Lin, Zheshuai; Yao, Jiyong; Zhang, Guochun
- Abstract
Two ferroborates Li5MSrFeB12O24 (M = Mg, Zn) crystallized in trigonal R3 space group, were obtained by high temperature solid state reaction. Centimeter‐level Li5MgSrFeB12O24 single crystals were grown from high temperature solution using Li2B4O7 as a self‐flux. In their structures, [FeO6] octahedra connect with [B2O6] chains by corner‐sharing O atoms forming the three‐dimensional [FeB12O24] framework. The family of ferroborates(III) was summarized and the structural comparison with Ba2MgB6O12 based on cation cosubstitution was also discussed to better understand the crystal structures of Li5MSrFeB12O24 (M = Mg, Zn). The transmittance spectrum of a Li5MgSrFeB12O24 crystal was measured to detect its transmittance window. In addition, thermal behaviors, other optical and magnetic characteristics of Li5MSrFeB12O24 (M = Mg, Zn) were discussed as well.
- Subjects
SINGLE crystals; CRYSTAL structure; HIGH temperatures; SPACE groups
- Publication
European Journal of Inorganic Chemistry, 2020, Vol 2020, Issue 17, p1676
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202000153