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- Title
Relaxation Dynamics and Magnetic Anisotropy in a Low-Symmetry Dy<sup>III</sup> Complex.
- Authors
Lucaccini, Eva; Briganti, Matteo; Perfetti, Mauro; Vendier, Laure; Costes, Jean‐Pierre; Totti, Federico; Sessoli, Roberta; Sorace, Lorenzo
- Abstract
The magnetic behaviour of a Dy(LH)3 complex (LH− is the anion of 2-hydroxy- N′-[( E)-(2-hydroxy-3-methoxyphenyl)methylidene]benzhydrazide) was analysed in depth from both theoretical and experimental points of view. Cantilever torque magnetometry indicated that the complex has Ising-type anisotropy, and provided two possible directions for the easy axis of anisotropy due to the presence of two magnetically non-equivalent molecules in the crystal. Ab initio calculations confirmed the strong Ising-type anisotropy and disentangled the two possible orientations. The computed results obtained by using ab initio calculations were then used to rationalise the composite dynamic behaviour observed for both pure DyIII phase and YIII diluted phase, which showed two different relaxation channels in zero and non-zero static magnetic fields. In particular, we showed that the relaxation behaviour at the higher temperature range can be correctly reproduced by using a master matrix approach, which suggests that Orbach relaxation is occurring through a second excited doublet.
- Subjects
MAGNETIC anisotropy; MOLECULAR dynamics; DYSPROSIUM compounds; PHENYL compounds; AB initio quantum chemistry methods; RARE earth metals
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 16, p5552
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201505211