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- Title
Heteronuclear 3 d/Dy<sup>III</sup> Coordination Clusters as Catalysts in a Domino Reaction.
- Authors
Griffiths, Kieran; Gallop, Christopher W. D.; Abdul ‐ Sada, Alaa; Vargas, Alfredo; Navarro, Oscar; Kostakis, George E.
- Abstract
Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2⋅2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]⋅2 CH3CN ( 3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.
- Subjects
COORDINATION compounds; DOMINO toppling; SECONDARY amines; NON-inertial frame; MAGNETIC properties
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 17, p6358
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201500505