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- Title
Synthesis and crystal and molecular structure of CdPhen( iso-C<sub>4</sub>H<sub>9</sub>OCS<sub>2</sub>)<sub>2</sub> and CdPhen( n-C<sub>4</sub>H<sub>9</sub>OCS<sub>2</sub>)<sub>2</sub> mixed-ligand complexes.
- Authors
Klevtsova, R. F.; Leonova, T. G.; Glinskaya, L. A.; Larionov, S. V.
- Abstract
Mixed-ligand complexes CdPhen( i-BuOCS2)2 (I) and CdPhen( n-BuOCS2)2 (II) have been synthesized. Their structures were solved using X-ray diffraction data (X8 APEX diffractometer, Mo K α radiation, 1641 and 2497 F hkl , R = 0.0359 and 0.0389). Crystals I are orthorhombic with unit cell parameters a = 6.5883(3) Å, b = 19.7123(10) Å, c = 20.1936(11) Å, V = 2622.6(2) Å3; Z = 4, space group Pbcn; crystals II are monoclinic, a = 6.5845(2) Å, b = 19.1522(6) Å, c = 20.7091(7) Å, β = 97.106(1), V = 2591.5(1) Å3, Z = 4, space group C2/ c. The structures consist of discrete mononuclear molecules in which the coordination polyhedron of the Cd atom is a distorted N2S4 octahedron. Molecular packing and interactions in the structures are discussed.
- Subjects
MATHEMATICAL crystallography; MOLECULAR structure; CHEMICAL structure; CRYSTALLOGRAPHY; SOLIDS
- Publication
Journal of Structural Chemistry, 2007, Vol 48, Issue 2, p267
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-007-0042-8