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- Title
[SBP]BF 4 Additive Stabilizing Zinc Anode by Simultaneously Regulating the Solvation Shell and Electrode Interface.
- Authors
Zhang, Xingyun; Su, Kailimai; Hu, Yue; Xue, Kaiyuan; Wang, Yan; Han, Minmin; Lang, Junwei
- Abstract
The zinc anode mainly faces technical problems such as short circuits caused by the growth of dendrite, low coulomb efficiency, and a short cycle life caused by side reactions, which impedes the rapid development of aqueous zinc-ion batteries (AZIBs). Herein, a common ionic liquid, 1,1-Spirobipyrrolidinium tetrafluoroborate ([SBP]BF4), is selected as a new additive for pure ZnSO4 electrolyte. It is found that this additive could regulate the solvation sheath of hydrated Zn2+ ions, promote the ionic mobility of Zn2+, homogenize the flux of Zn2+, avoid side reactions between the electrolyte and electrode, and inhibit the production of zinc dendrites by facilitating the establishment of an inorganic solid electrolyte interphase layer. With the 1% [SBP]BF4-modified electrolyte, the Zn||Zn symmetric cell delivers an extended plating/stripping cycling life of 2000 h at 1 mA cm−2, which is much higher than that of the cell without additives (330 h). As a proof of concept, the Zn‖V2O5 battery using the [SBP]BF4 additive shows excellent cycling stability, maintaining its specific capacity at 97 mAh g−1 after 2000 cycles at 5 A g−1, which is much greater than the 46 mAh g−1 capacity of the non-additive battery. This study offers zinc anode stabilization through high-efficiency electrolyte engineering.
- Subjects
ZINC electrodes; ZINC; ANODES; SOLID electrolytes; ELECTRODES; SOLVATION; TETRAFLUOROBORATES; ZINC ions
- Publication
Batteries, 2024, Vol 10, Issue 3, p102
- ISSN
2313-0105
- Publication type
Article
- DOI
10.3390/batteries10030102