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- Title
A Study on the Photochemical Transformations of p- and m-Nitrosonitrobenzenes.
- Authors
Zelentsov, S. V.; Logunov, A. A.
- Abstract
Photochemical oxidation of p- and m-nitrosonitrobenzenes to corresponding dinitrobenzenes was studied. The reaction was described by a scheme involving two successive steps, with the rates of photochemical decomposition of isomeric nitrosonitrobenzenes being much higher than those of dinitrobenzenes. Oligomeric azo and azoxy compounds and the products of hydroxylation of the reaction medium were found as final products of the reaction upon long-term irradiation with UV light.
- Subjects
DINITROBENZENES; NITROBENZENE; BENZENE; NITRO compounds; HYDROXYLATION; CHEMICAL reactions; ULTRAVIOLET radiation; RADIATION; PHOTOCHEMISTRY
- Publication
High Energy Chemistry, 2005, Vol 39, Issue 4, p244
- ISSN
0018-1439
- Publication type
Article
- DOI
10.1007/s10733-005-0049-7