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- Title
Recent Advances in the Synthesis of SCF<sub>2</sub>H- and SCF<sub>2</sub>FG-Containing Molecules.
- Authors
Xiong, Heng ‐ Ying; Pannecoucke, Xavier; Besset, Tatiana
- Abstract
In recent years, much interest has been paid to difluoromethylthiolated molecules as the 'SCF2' moiety is a key motif in drug and agrochemical research. Consequently, the development of versatile strategies for the selective synthesis of SCF2H- and SCF2FG-containing molecules (FG=functional group) has attracted a lot of attention and inspired the scientific community to design new tools. This Minireview highlights the major progress made in this field. Particularly, methodologies developed for the difluoromethylation of sulfur-containing molecules and the direct construction of C−SCF2 bonds in various classes of compounds are showcased and discussed.
- Subjects
ORGANOFLUORINE compounds; FUNCTIONAL groups; CHEMICAL synthesis; AGRICULTURAL chemicals; MOLECULES
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 47, p16734
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201603438