N-(5-Bromopyridyl-2)-2- N′-cytisino-and N′- d-pseudoephedrineoacetamides were synthesized by reaction of the alkaloids cytisine and d-pseudoephedrine with N-(5-bromopyridin-2-yl)-2-bromoacetamide hydrobromide. The compositions and structures of the products were confirmed by IR and PMR spectroscopy and mass spectrometry.